WO2023175512 - POLYOXOMETALATE COMPLEXED METAL OXIDES AND USE THEREOF

National phase entry:
Publication Number WO/2023/175512
Publication Date 21.09.2023
International Application No. PCT/IB2023/052481
International Filing Date 14.03.2023
Title **
[English] POLYOXOMETALATE COMPLEXED METAL OXIDES AND USE THEREOF
[French] OXYDES MÉTALLIQUES COMPLEXÉS DE POLYOXOMÉTALATE ET LEUR UTILISATION
Applicants **
B. G. NEGEV TECHNOLOGIES AND APPLICATIONS LTD., AT BEN-GURION UNIVERSITY
Inventors
LEFFLER, Nitai
WEINSTOCK, Ira Alan
Priority Data
63/319,457   14.03.2022   US
63/477,323   27.12.2022   US
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Quotation for National Phase entry

Country StagesTotal
China Filing, Examination, Granting3216
EPO Filing, Examination, Granting24546
Japan Filing, Examination, Granting2856
South Korea Filing, Examination, Granting3597
USA Filing, Examination, Granting8140
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Total: 42,355

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Abstract[English] Complexes of polyoxometalate (POM) cluster anions and nanoparticle (NP) cores, are disclosed, featuring inherent thermodynamic stability at least due to covalent bonds, which attach the POMs to the NP cores. The nanoparticles coprise a plurality of crystalline, polycrystalline or amorphous metal-oxide, metal oxyhydroxide and/or metal hydroxide compounds. The POM and NP, each independently, may comprise one, two, three or more different metal cations, particularly transition or main group metal cations. These complexes are highly soluble in water and inherently stable to oxidation and hydrolysis in a broad pH range. As such, the complexes are usfule, inert alia, as improved soluble water-oxidation catalysts and stabilizers of metastable crystals.[French] L'invention concerne des complexes d'anions en grappe de polyoxométalate (POM) et de noyaux de nanoparticules (NP), présentant une stabilité thermodynamique inhérente au moins due à des liaisons covalentes, qui fixent les POM aux noyaux NP. Les nanoparticules se composent d'une pluralité de composés cristallins, d'oxyde métallique polycristallin ou amorphe, d'oxyhydroxyde métallique et/ou d'hydroxyde métallique. Le POM et le NP, chacun indépendamment, peuvent comprendre un, deux, trois cations métalliques différents ou plus, en particulier des cations métalliques de transition ou de groupe principal. Ces complexes sont hautement solubles dans l'eau et intrinsèquement stables à l'oxydation et à l'hydrolyse dans une large plage de pH. En tant que tels, les complexes sont utiles, entre autres, en tant que catalyseurs solubles d'oxydation dans l'eau améliorés et stabilisants de cristaux métastables.

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